Entonox


  • A compressed gas mixture of 50% oxygen and 50% nitrous oxide by volume

  • Analgesia:
    • Pre-hospital
    • Labour ward
    • Emergency department
    • Other areas e.g. burns unit for dressing changes

  • Nitrous oxide and oxygen dissolve into each other don't behave in the way that would be predicted from their individual properties
  • Oxygen is bubbled through liquid nitrous oxide, with vaporisation of the liquid nitrous oxide to form Entonox
  • The mixture has a critical temperature and pressure different to that of either individual gas

  • Compressed into blue cylinders with white/blue quartered shoulders at 13,700kPa
  • In theory shouldn't be able to make nitrous oxide gaseous at this pressure because it is below its critical temperature (36.5'C) and above its critical pressure (72bar)
  • However the Poynting effect confers a pseudocritical temperature of -7ºC
  • Therefore the nitrous oxide is above its critical temperature and can be gaseous at this pressure

Safe storage

  • Separation of Entonox into its liquid components occurs if the temperature is decreased to below 5.5ºC
    • This is most likely at a pressure of 117bar; separation is less likely at pressures above or below 117bar
    • At 4bar the pseudocritical temperature is -30ºC
  • Separation can be dangerous as it causes the cylinder to contain:
    • A gas with high oxygen content, which is initially breathed off first
    • A liquid with maximum 20% oxygen content e.g. a hypoxic mixture that is breathed off once the initial gas has been removed

  • Therefore entonox storage should involve:
    • Horizontal cylinder placement to increase area for diffusion
    • An environment above 5ºC - 10ºC for 24hrs before use
    • A dip tube whose tip is at the base of the cylinder, causing the liquid nitrous oxide to be used first and prevent administration of hypoxic gas mixtures

  • A two-stage pressure demand regulator is attached to the cylinder
    1. First stage is a pressure-reducing valve
    2. The second stage is a demand valve, which allows gas to flow when the pressure is below atmospheric pressure

  • As the patient breaths in, gas flow is allowed to occur
  • Gas flow stops at the end of inspiration